\documentclass[12pt,a4paper]{article}
\usepackage[dvips]{color}
\usepackage{multicol}
\pagestyle{empty}
\setlength{\oddsidemargin}{0pt}
\setlength{\textwidth}{16cm}
\setlength{\textheight}{22cm}
\setlength{\parindent}{0pt}
\setlength{\parskip}{0pt}
 
\begin{document}
\renewcommand*{\DefineNamedColor}[4]{%
   \textcolor[named]{#2}{\rule{7mm}{7mm}}\quad
   \texttt{#2}\strut\\}
 
\begin{center}\Large Named colours in\texttt{dvipsnam.def}
\end{center}
\begin{multicols}{3}
\input{dvipsnam.def}
\end{multicols}
\end{document}

